Mineral Database

Mineral Database
Mineralogy of Wales

Ferroglaucophane

Crystal System: Monoclinic
Formula: Na2(Fe2+,Mg)3Al2Si8O22(OH)2
Status of Occurrence: Confirmed Occurrence - 1st UK recording
Distribution: Rare
Chemical Composition: Sodium iron aluminium silicate hydroxide
Method(s) of Verification: Llanfairpwllgwyngyll - EMPA (Gibbons & Gyopari, 1986; Horák & Gibbons, 1986).
Chemical Group:
  • Silicates
Geological Context:
  • Metamorphic
Introduction: ferroglaucophane belongs to the amphibole group, and is a sodic amphibole which forms a series with ferroglaucophane. It should be noted that many analyses previously classified as crossite (abandoned term) are now identified as glaucophane/ferroglaucophane. Ferroglaucophane occurs in rocks that have been metamorphosed under high pressure conditions (equivalent to burial at depths of approximately 24 km to more than 60 km) and is a diagnostic mineral of the blueschist facies, but survives into the eclogite facies. Glaucophane/ferroglaucophane provide the blue colour characteristic of blueschists and are typically found with a combination of the following minerals lawsonite, chlorite, garnet, albite, zoisite, phengitie and paragonite mica.
Occurrence in Wales: Blake (1888) provided the first description of glaucophane from the British Isles, reporting its occurrence in rocks of his ‘Monian System’ [now known as the Aethwy Terrane or Blueschist Belt, (Gibbons & Horák, 1990)] from near Llanfairpwllgwyngyll, Anglesey. Blake’s identification was confirmed by Greenly (1919) who also noted zoning in the amphiboles with green ‘hornblende’ core passing outwards into blue rims. Holgate (1951) provided a chemical analysis on separated rims, but suggested that as the blue amphibole contained a higher Fe3+ to Aliv content, it was crossite and not glaucophane. Macpherson (1983) recalculated Holgate’s analysis and, applying the new IMA amphibole classification, deemed them to be magnesio-arfvedsonites. New microprobe data (Horák & Gibbons, 1986; Gibbons & Gyopari, 1986) showed that the rims fall within the crossite-glaucophane-ferroglaucophane series, now revised to the glaucophane-ferroglaucophane series. The Anglesey blueshists occur as poorly-exposed scattered outcrops forming a NE-SW oriented belt in the south of the island. Although blue amphibole can be found throughout this zone, in rocks of suitable composition, only two areas near Llanfairpwllgwyngyll have been described in any detail (Blake, 1888, Greenly, 1919, Horák & Gibbons, 1996; Gibbons & Gyopari, 1986). They have particular significance in that they are Precambrian in age (Dallmeyer & Gibbons, 1987) and represent some of the oldest blueschists in the World, having formed during subduction on the Proterozoic margin of the supercontinent Gondwanaland (Gibbons & Horák, 1996).
Key Localities:
  • Llanfairpwllgwyngyll, Anglesey: crags below the Marquis of Anglesey’s Column (The Monument) are composed of fine-grained, dark-grey schist. These amphibole-epidote schists contain minor quartz, chlorite, titanite, hematite and magnetite, but most of these minerals are not clearly discernible in hand specimen. In thin section the blue amphibole forms a mass of beautiful, euhedral, lavender-blue crystals, typically less than 1 mm in size, which has overgrown euhedral or anhedral green amphibole cores (see barroisite-ferrobarroiste-winchite entries). The Marquis of Anglesey’s Column area is a protected site and no collecting or access with hammers is permitted. Those wishing to study or view specimens should contact the National Museum of Wales (http://www.nmgw.ac.uk/geology/ask.en.shtml). Road-side exposures of blueschist, on the A5 at Llanfairpwllgwyngyll, many showing three stages of amphibole development (actinolite core rimmed by barroisite and in turn rimmed by glaucophane/ferroglaucophane), were described by Gyopari (1984) and Gibbons & Gyopari (1986).
References:
  • Blake, J.F., 1888 The occurrence of glaucophane-bearing rocks in Anglesey.  Geological Magazine, 5, 125-127.
  • Dallmeyer, R.D. & Gibbons, W., 1987 The age of blueschist metamorphism in Anglesey, North Wales: evidence from 40Ar/39Ar mineral dates of the Penmynydd schists.  Journal of the Geological Society, London, 144, 843-850.
  • Gibbons, W. & Gyopari, M., 1986 A greenschist protolith for blueschist on Anglesey, U.K.  In: Evans, B.W. & Brown, E.H. (eds), Blueschist and Eclogites. Geological Society of American Memoir, 164, 217-228.
  • Gibbons, W. & Horák, J.M., 1990 Contrasting metamorphic terranes in NW Wales.  In D'Lemos, R.D., Strachan, R.A., Topley, C.G. and Beckinsale, R.D. eds, The Cadomian Orogeny, Geological Society of London, Special Publication No. 51, 315-327.
  • Greenly, E., 1919 The Geology of Anglesey.  Memoirs of the Geological Survey of Great Britain, 980pp (2 volumes).
  • Holgate, N., 1951 On crossite from Anglesey.  Mineralogical Magazine, 29, 792-798.
  • Horak, J.M. & Gibbons, W., 1986 Reclassification of blueschist amphiboles from Anglesey, North Wales.  Mineralogical Magazine, 50, 532-535.
  • Macpherson, H.G., 1983 References for, and updating of L.J. Spenser’s 1st and 2nd supplimentary list of British Minerals.  Mineralogical Magazine, 47, 243-257.
  • Rock, N.M.S. & Leake, B.E., 1979 A FORTRAN program for the classification of amphiboles according to IMA (1978).  IGS Petrographic Report 560124 (unpublished).